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Two main terms for “fire” are reconstructible for Proto-Indo-European: *h₁n̥gʷnís and *péh₂wr̥. They are usually considered in semantic opposition. The first term is usually masculine and refers to fire as something animate and active (compare Agni, the most prominent Old Indic deity), whereas the second term is neuter and refers to fire as something inanimate and passive, i.e. as a substance.
Mayrhofer, Manfred (1992) Etymologisches Wörterbuch des Altindoarischen [Etymological Dictionary of Old Indo-Aryan] (in German), volume 1, Heidelberg: Carl Winter Universitätsverlag, page 44