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English
Etymology
From bowtie and arene; compare pillararene, calixarene etc.
Noun
bowtiearene (uncountable)
- (organic chemistry) A macrocycle composed of a fluorophore suspended in a pillararene
2019 December 5, Sheng‐Nan Lei, Xiao Hongyan, Zeng Yi, Tung Chen-Ho, Wu Li-Zhu, Cong Huan, “BowtieArene: A Dual Macrocycle Exhibiting Stimuli‐Responsive Fluorescence”, in Angewandte Chemie International Edition, volume 59, →DOI:Here we present BowtieArene, a novel fluorescent dual macrocycle, featuring a central tetraphenylethylene‐derived fluorophore and two pillar‐like, pentagon‐shaped cavities which are comparable to pillararene.
2020, Ono, Toshikazu, and Yoshio Hisaeda, “Vapochromism of Organic Crystals Based on Macrocyclic Compounds and Inclusion Complexes”, in Symmetry, volume 12, →DOI, page 1903:Another example of pillararenes modification with a fluorescent material is the so-called BowtieArene, which consists of a tetraphenylethylene (TPE) fluorophore and two pillararenes
2020, Lou, Xin‐Yue, and Ying‐Wei Yang, “Aggregation‐induced emission systems involving supramolecular assembly”, in Aggregate, →DOI:A new fluorescent dual macrocycle, denoted as bowtiearene, was recently reported by Cong and coworkers as a combination of TPE moieties and pillararene rings
2021, Wu, Jia‐Rui, and Ying‐Wei Yang, “Synthetic Macrocycle‐Based Nonporous Adaptive Crystals for Molecular Separation”, in Angewandte Chemie International Edition, volume 60, →DOI:[…] new NACs based on pillararene derivatives and other important synthetic macrocycles, such as biphenarene, leaning pillararene (i.e., leaning towerarene), geminiarene, bowtiearene, cucurbituril, hybridarene, and tiaraarene have been developed and recently reported.