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Borrowed from Frenchnicotine, equivalent to Nicot + -ine, named after Jean Nicot (1530–1604), the French ambassador to Portugal, who sent tobacco seeds back to France in 1561. The etymology of the surname itself is unclear.
2004 April 13, Nick Paton Walsh, “Ample Alyona shakes up Russian pageant”, in The Guardian:
The website calls a vote for Alyona a vote against "beauties who do not look natural and who cannot be distinguished from each other" and rails against the "imposed standards" of 90-60-90 vital statistics, and "cigarettes with out nicotine and coffee without caffeine".