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This is the traditional popular spelling in the UK and India, and an alternative spelling in Canada, Australia and New Zealand. However, it is considered non-standard in scientific contexts, as the IUPAC has only approved the spelling sulfur.
According to De Vaan citing Szemerényi, perhaps from an s-stem Proto-Indo-European*sélpos. However, De Vaan finds both the -él- > -ól- and -os > -ur changes to be irregular (for -ol- > -ul- see sulcus), adding that perhaps it comes from Proto-Italic*solpor, from an r/n-stem Proto-Indo-European*sólpr̥ instead.
^ De Vaan, Michiel (2008) Etymological Dictionary of Latin and the other Italic Languages (Leiden Indo-European Etymological Dictionary Series; 7), Leiden, Boston: Brill, →ISBN
“sulphur”, in Charlton T. Lewis and Charles Short (1879) A Latin Dictionary, Oxford: Clarendon Press
“sulphur”, in Charlton T. Lewis (1891) An Elementary Latin Dictionary, New York: Harper & Brothers