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Possible metathesis of *h₁wes-(“good”), or perhaps related to *h₁es-(“to be”).[1]
Hittite𒀀𒀸𒋗𒍑(āššuš, “good”) and possibly Epic Greekἠΰς(ēǘs, id.) provide strong evidence for a u-stem adjective *h₁óh₁s-u-s, gen.sg. *h₁h₁s-éw-s,[2] which would point to a reduplicated root *h₁es-. Since Proto-Indo-European apparently did not allow geminate clusters, the weak stem would have simplified to *h₁s-éw-; this could be the source of the combining form *h₁su-, with which it would be identical in the zero-grade.
Proto-Hellenic: *ehu- (see there for further descendants)
Proto-Indo-Iranian: *Hsu- (see there for further descendants)
→ Old Armenian: հ-(h-)(or inherited and contaminated with the Iranian)
References
^ Wodtko, Dagmar S., Irslinger, Britta, Schneider, Carolin (2008) “h₁u̯es-”, in Nomina im indogermanischen Lexikon [Nouns in the Indo-European Lexicon] (in German), Heidelberg: Universitätsverlag Winter, pages 686-690
^ Kloekhorst, Alwin (2008) “āššu- / āššau̯-”, in Etymological Dictionary of the Hittite Inherited Lexicon (Leiden Indo-European Etymological Dictionary Series; 5), Leiden, Boston: Brill, →ISBN, pages 223–225