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First found from the Egyptiots Aretaios and Dioskurides, a borrowing from Copticⲕⲁⲕⲉ(kake), ⲕⲉⲕⲉⲓ(kekei, “darkness”) from Egyptiankkw(“darkness”), acknowledging its providing shade in the desert, with a preformative analogical to ἄκανθα(ákantha).
Kramer, Johannes (2010) “10. ἀκακία, ἄκανθα / acacia, acantha”, in Von der Papyrologie zur Romanistik (Archiv für Papyrusforschung und verwandte Gebiete; Beiheft 30), De Gruyter, →ISBN, page 155
“ἀκακία – Acacia sp.”, in Dioscórides Interactivo (in Spanish), 2024
Etymology 2
From ἄκακος(ákakos, “without malice”), from ἀ-(a-, “not”) + κακός(kakós, “evil”).