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Russian: змей(zmej) (see there for further descendants)
References
Sreznevsky, Izmail I. (1893) “змии”, in Матеріалы для Словаря древне-русскаго языка по письменнымъ памятникамъ [Materials for the Dictionary of the Old East Slavic Language Based on Written Monuments] (in Russian), volume 1 (А – К), Saint Petersburg: Department of Russian Language and Literature of the Imperial Academy of Sciences, column 986