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Simplified from an earlier мозг(mozg), with final -г devoiced (as usual for word-final voiced stops) and later interpreted as the diminutive suffix -ък(-ǎk). Ultimately, inherited from Proto-Slavic*mozgъ.
Georgiev, Vladimir I., Duridanov, I. V., editors (1995), “мозък”, in Български етимологичен речник [Bulgarian Etymological Dictionary] (in Bulgarian), volume 4 (мѝнго² – па̀дам), Sofia: Prof. Marin Drinov Pubg. House, →ISBN, page 207