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The expected outcome of inherited *ph₃tós would be *patos (with *CHC > *CəC > *CaC; compare *katos from PIE *ḱh₃tós); therefore *pōtos must either be independently derived from the root or result from the spread of *pō- throughout the paradigm (being reanalyzed as the root).[Note 1]
^ De Vaan explains: “The full grade of pōtus ‘drunk’ must have been introduced from the root aorist. Pōtus and pō-culum have caused the spread of pō- in the other derivatives.”
References
^ De Vaan, Michiel (2008) “pōtus”, in Etymological Dictionary of Latin and the other Italic Languages (Leiden Indo-European Etymological Dictionary Series; 7), Leiden, Boston: Brill, →ISBN, page 485: “PIt. *pōto- ‘drunk’”