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Having many angles; hence characteristic of a polygon.
1851, Frederick Overman, “Blast Pipes”, in The Manufacture of Iron, in All its Various Branches. , 2nd edition, Philadelphia: Henry C. Baird, page 413:
Various forms of conductors have been invented, such as wooden and iron pipes, of a round, square, and polygonal section; but at present, scarcely any other than sheet or cast iron pipes are employed.
Comprised of polygons.
1906, James George Frazer, Attis, Otis, Osiris, page 154: